Safety data sheet for Dichloromethane

CAS 75-09-2

This is the free preview of a draft SDS for Dichloromethane — Sections 1, 2 and 9, generated from the sources named below. The full 16-section draft, with your own company in Section 1, is $5 per document.

Typically documented by: Paint stripping, degreasing, laboratory use.

Draft safety data sheet — preview

Sections 1, 2, 9 of 16

CAS number
75-09-2
Molecular formula
CH2Cl2
Molecular weight
84.93 g/mol
Signal word
Warning

Hazard classification

  • GHS07 — Health hazard — irritant
  • GHS08 — Serious health hazard
  • H315: Causes skin irritation.
  • H319: Causes serious eye irritation.
  • H336: May cause drowsiness or dizziness.
  • H351: Suspected of causing cancer.

Section 1 — Identification

1.1 Product identifier

Product identifier: Dichloromethane

Chemical name (IUPAC): dichloromethane

CAS number: 75-09-2

PubChem CID reference: 6344

Synonyms: DICHLOROMETHANE; Methylene chloride; Methylene dichloride; Methane, dichloro-; Methylene bichloride; Methane dichloride; Solaesthin; Solmethine; Narkotil; Aerothene MM

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: Laboratory reagent, industrial processing aid, formulation component, and internal product-stewardship review subject to supplier confirmation.

Uses advised against: Consumer, medical, food, or any other use not covered by the supplier's label, technical instructions, or exposure scenario.

Section 2 — Hazards Identification

2.1 Classification of the substance or mixture

Classification basis: OSHA 29 CFR 1910.1200 Appendix A, aligned to the GHS Rev. 7 hazard classes.

Classification: Skin Irritation, Category 2 (Skin Irrit. 2) [H315]

Classification: Eye Irritation, Category 2 (Eye Irrit. 2) [H319]

Classification: Specific Target Organ Toxicity, Single Exposure, Category 3 (STOT SE 3) [H336]

Classification: Carcinogenicity, Category 2 (Carc. 2) [H351]

2.2 Label elements

Signal word: Warning

GHS pictograms: GHS07 (Exclamation), GHS08 (Health Hazard)

Hazard statement: H315: Causes skin irritation.

Hazard statement: H319: Causes serious eye irritation.

Hazard statement: H336: May cause drowsiness or dizziness.

Hazard statement: H351: Suspected of causing cancer.

Precautionary statement: P260: Do not breathe dust/fume/gas/mist/vapors/spray.

Precautionary statement: P264+P265: Wash hands thoroughly after handling. Do not touch eyes.

Precautionary statement: P280: Wear protective gloves, protective clothing, eye protection, face protection, and hearing protection.

Precautionary statement: P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

Precautionary statement: P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

Precautionary statement: P302+P352: IF ON SKIN: Wash with plenty of water.

Section 9 — Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Physical form: Liquid

Appearance: Colorless liquid [Note: A gas above 104 degrees F]

Odor: Sweet, pleasant odor, like chloroform

Boiling point: 39.8°C (104°F) at 1013 hPa

Melting point: -95°C (-139°F)

Flash point: Not available

Density: 1.3255 20 °C/4 °C

Vapor pressure: 587 hPa at 25°C

Water solubility: Miscible

Log Pow (log Kow): 1.25

Vapor density: 2.93 (air = 1)

Lower explosive limit: 15.5%

Upper explosive limit: 66.4%

Auto-ignition temperature: 556°C (1033°F)

Viscosity: 0.437 mPa.s at 20 °C

pH: Not available

9.2 Other information

Other information: Additional classification-supporting physical hazard data should be confirmed from the customer-specific product specification where required.

Sources

  • ECHA C&L Inventory — harmonised CLP entry
  • PubChem — GHS classification
  • PubChem — compound record
  • PubChem — names and identifiers
  • PubChem — regulatory information
  • PubChem — toxicity data
  • PubChem — transport information

Sections 1.3 and 1.4 are withheld here because the supplier and emergency contact blocks carry your own company details in the draft you buy. Every draft needs review by a competent person before it is issued.

Measured values for Dichloromethane, and where each one comes from

31 measured values for 11 properties, read from 4 public databases. On 4 properties the records differ. Each reading is shown with its own record. Follow any record to read the value at its source.

Boiling point

4 records agree

Used with vapour pressure to judge how readily the substance reaches the air you breathe.

Melting point

4 records, -97 to -95 °C

Fixes the physical state at handling temperature, which the label and the transport class depend on.

Auto-ignition temperature

1 record

The temperature at which the substance ignites with no spark or flame. It sets safe surface and process temperatures.

Explosive limits

1 record

The vapour concentration range in air that will burn. Below the lower limit and above the upper limit it will not.

Upper 66.4% in oxygen; lower 15.5% in oxygen
Hazardous Substances Data Bank (HSDB)

Vapour pressure

4 records differ

The higher it is, the faster the substance evaporates into the workplace air at room temperature.

750 [mm Hg] @39.299999999999997 °C
PAC Chemical Database, U.S. Department of Energy

Vapour density

2 records differ

Above 1 the vapour sinks and collects in pits, sumps and low enclosed spaces.

Density

4 records differ

Needed to convert between mass and volume on the label, in transport papers and in a spill estimate.

Solubility

5 records, each a different case

Determines spill behaviour, the right extinguishing media and the correct first-aid rinse.

In water, 13,200 mg/L at 25 °C
Hazardous Substances Data Bank (HSDB)
In water, 13,000 mg/L at 25 °C
Hazardous Substances Data Bank (HSDB)
Miscible with alcohol, ether, dimethylformamide
Hazardous Substances Data Bank (HSDB)
Miscible with ethanol; soluble in carbon tetrachloride
Hazardous Substances Data Bank (HSDB)

Partition coefficient (log Kow)

1 record

Indicates whether the substance accumulates in fat or in water, which drives the environmental sections.

Viscosity

1 record

Governs how far a spill spreads and how fast it soaks into a surface or a sorbent.

Odour

4 records, each a different case

Odour is a warning property only. Many substances are hazardous well below the concentration you can smell.

Sweet, pleasant odor, like chloroform
Hazardous Substances Data Bank (HSDB)
Penetrating ether-like odor
Hazardous Substances Data Bank (HSDB)
Slightly sweet smell, similar to that of trichloromethane
Hazardous Substances Data Bank (HSDB)

These are the public records read for Dichloromethane, published here unchanged. Where two records disagree, the draft you buy states the value and names the record behind it, so a reviewer can see what was chosen. Every draft needs review by a competent person before it is issued.

Get the full draft SDS for Dichloromethane

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